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Creators/Authors contains: "Vellalath, Sreekumar"

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  1. ; ; ; (, Organic Letters)
    null (Ed.)
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  2. ; ; ; (, Tetrahedron)
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  3. ; ; ; (, Angewandte Chemie International Edition)
    Abstract Medium‐sized lactams are important structural motifs found in a variety of bioactive compounds and natural products but are challenging to prepare, especially in optically active form. A Michael addition/proton transfer/lactamization organocascade process is described that delivers medium‐sized lactams, including azepanones, benzazepinones, azocanones, and benzazocinones, in high enantiopurity through the intermediacy of chiral α,β‐unsaturated acylammonium salts. An unexpected indoline synthesis was also uncovered, and the benzazocinone skeleton was transformed into other complex heterocyclic derivatives, including spiroglutarimides, isoquinolinones, and δ‐lactones. 
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